The black Volkswagon Golf crashed into the silver Ford Mondeo and a shop in Ewell Road in Surbiton at about 4.38am.
Police said approximately a minute earlier the car had failed to stop for police when indicated to do so close to the junction with Ditton Road.
The Golf was being driven by a man believed to be in his mid 20s.
He suffered a head injury and was taken to hospital.
No police officers were injured.
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